There are several dedicated packages to typeset a curriculum vitæ or a resume in LaTeX, such as europecv or ecv. For some reason I’ve always found these solutions not flexible enough to suit my needs. This is why I opted for a standard (article) class as a basis for my CV.
Some TeX distributions such as XeTeX allow you not only to benefit of the advanced typesetting features included in LaTeX, but also to use in your documents expert fonts such as Hoefler Text, Adobe Minion, or Adobe Garamond Pro and to edit TeX sources in your native (Western or non-Western) writing system.
